Other metals may be rendered passive; for example, zinc does not precipitate copper from solutions of the double cyanides and sulphocyanides, nickel and cadmium from the nitrates, and iron from the sulphate, but it immediately throws down nickel and cadmium from the sulphates and chlorides, and lead and copper from the nitrates (see 0.
He also experimented with nickel and again found a resemblance to the strain curve.
Small amounts of nickel and cobalt are often present.
This salt may be used for the separation of cobalt and nickel, since the latter metal does not form a similar double nitrite, but it is necessary that the alkaline earth metals should be absent, for in their presence nickel forms complex nitrites containing the alkaline earth metal and the alkali metal.
Numerous methods have been devised for the separation of nickel and cobalt, the more important of which are: -the cobaltinitrite method by which the cobalt is precipitated in the presence of acetic acid by means of potassium nitrite (the alkaline earth metals must not be present); the cyanide method (J.
The vapour of nickel carbonyl burns with a luminous flame, a cold surface depressed in the flame being covered with a black deposit of nickel.
Of the rarer bismuth minerals we may notice the following: - the complex sulphides, copper bismuth glance or wittichenite, BiCu 3 S 3, silver bismuth glance, bismuth cobalt pyrites, bismuth nickel pyrites or saynite, needle ore (patrinite or aikinite), BiCuPbS 3, emplectite, CuBiS 2, and kobellite, BiAsPb 3 S 6; the sulphotelluride tetradymite; the selenide guanajuatite, B12Se3, Iv.
There is some roofing slate along the Rogue river, natural cement, nickel ore, bismuth and wolframite in Douglas county, gypsum in Baker county, fire-clay in Clatsop county, borate of soda on the marsh lands of Harney county, infusorial earth and tripoli in the valley of the Deschutes river, chromate of iron in Curry and Douglas counties, molybdenite in Union county, bauxite in Clackamas county, borate of lime in Curry county, manganese ore in Columbia county, and asbestos in several of the southern and eastern counties.
For very accurate work it is desirable that the base-plate, the slide and the scale should be of nickel steel, having the same thermal coefficient of expansion as glass.
Normal values of K were given by nitrogen peroxide, N204, sulphur chloride, S 2 C1 21 silicon tetrachloride, SiC1 4, phosphorus chloride, PC1 3, phosphoryl chloride, POC1 31 nickel carbonyl, Ni(CO) 4, carbon disulphide, benzene, pyridine, ether, methyl propyl ketone; association characterized many hydroxylic compounds: for ethyl alcohol the factor of association was 2.74-2.43, for n-propyl alcohol 2.86-2.72, acetic acid 3.62 -2.77, acetone 1 .