Sentence Examples with the word hydroxyl group

By the action of phosphorus pentachloride, the hydroxyl group is replaced by chlorine.

This is filtered, washed, and then fused with caustic soda, when the sulpho-group is replaced by a hydroxyl group, and a second hydroxyl group is simultaneously formed; in order to render the formation of this second group easier, a little potassium chlorate or sodium nitrate is added to the reaction mixture.

The hydroxyl group is more reactive than in the phenols, the naphthols being converted into naphthylamines by the action of ammonia, and forming ethers and esters much more readily.

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On the chromophoreauxochrome theory (the nitro group being the chromophore, and the hydroxyl the auxochrome) it is necessary in order to explain the high colour of the metallic salts and the colourless alkyl and aryl derivatives to assume that the auxochromic action of the hydroxyl group is only brought strongly into evidence by salt formation.

Thus a double bond of oxygen, as in the carbonyl group CO, requires a larger volume than a single bond, as in the hydroxyl group - OH, being about 12.2 in the first case and 7.8 in the second.

The hydrogen of the hydroxyl group in phenol can be replaced by metals, by alkyl groups and by acid radicals.

The meta-nitrocompound, which is precipitated last, is then reduced, and the amino group so formed is replaced by the hydroxyl group by means of the Sandmeyer reaction.

Substituting one hydroxyl group into each of these residues, we obtain radicals of the type - CH 2.

Only two are known containing the hydroxyl group in the pyridine nucleus, namely, carbostyril (a-oxyquinoline), which is formed by the reduction of ortho-aminocinnamic acid with ammonium sulphide (L.

An important class of compounds, termed amines (q.v.), results from the condensation of alcohols with ammonia, water being eliminated between the alcoholic hydroxyl group and a hydrogen atom of the ammonia.