Sentence Examples with the word benzenoid

From the fact that reduction products containing either one or two double linkages behave exactly as unsaturated aliphatic compounds, being readily reduced or oxidized, and combining with the halogen elements and haloid acids, it seems probable that in benzenoid compounds the fourth valencies are symmetrically distributed in such a manner as to induce a peculiar stability in the molecule.

This and other facts connected with the stability of benzenoid compounds are clearly shown when we consider mixed aliphatic-aromatic hydrocarbons, i.e.

The molecule is aromatic but not benzenoid; however, by the reduction of one half of the molecule, the other assumes a benzenoid character.

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Meyer (Ber., 18 94, 2 7, p. 510 et seq.) showed that in benzenoid compounds ortho-substituents exert a great hindering effect on the esterification of alcohols by acids in the presence of hydrochloric acid, this hindering being particularly marked when two substituents are present in the ortho positions to the carboxyl group. In such a case the ester is best prepared by the action of an alkyl halide on the silver salt of the acid, and when once prepared, can only be hydrolysed with great difficulty.

Systems which are generally unsaturated compounds, often of considerable stability, and behave as nuclei; these compounds constitute a well-individualized class exhibiting closer affinities to benzenoid substances than to the open-chain series.

For general purposes, however, the symbol (2), in which the lateral rings are benzenoid and the medial ring fatty, represents quite adequately the syntheses, decompositions, and behaviour of anthracene.

It is difficult to determine which configuration most accurately explains the observed facts; Kekule's formula undoubtedly explains the synthetical production of benzenoid compounds most satisfactorily, and W.

Hitherto we have generally restricted ourselves to syntheses which result in the production of a true benzene ring; but there are many reactions by which reduced benzene rings are synthesized, and from the compounds so obtained true benzenoid compounds may be prepared.

The stronger argument against the ethylenoid linkages demanded by Kekule's formula is provided by the remarkable stability towards oxidizing and reducing agents which characterizes all benzenoid compounds.

X u x?X x x HZ which exist between aliphatic and benzenoid compounds make the transformations of one class into the other especially interesting.