Sentence Examples with the word asymmetric

This formula, which necessitates the presence of two asymmetric carbon atoms in an alkyl tetrahydroberberine, has been accepted by M.

The aldehyde group reacts with hydrocyanic acid to produce two stereo-isomeric cyanhydrins; this isomerism is due to the conversion of an originally non-asymmetric carbon atom into an asymmetric one.

The plane projection of molecular structures which differ stereochemically is discussed under Stereoisomerism; in this place it suffices to say that, since the terminal groups of the hexaldose molecule are different and four asymmetric carbon atoms are present, sixteen hexaldoses are possible; and for the hexahydric alcohols which they yield on reduction, and the tetrahydric dicarboxylic acids which they give on oxidation, only ten forms are possible.

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Since the acid contains an asymmetric carbon atom, it can exist in three forms, a dextro-rotatory, a laevo-rotatory and an inactive form; the acid obtained in the various synthetical processes is the inactive form.

Absence of rotary power when asymmetric carbon atoms are present, may be caused by an internal compensation within the molecule as with the inactive tartaric acid (mesotartaric acid), or may be due to the fact that the compound is an equimolecular mixture of leftand right-hand varieties, this being the case with racemic acid that was broken by Louis Pasteur into laevoand dextro-tartaric acid (see Stereo-Isomerism).

It was a melancholy, asymmetric ballad, and reminded me of British jazz from the 1960s.

The proof of this statement rests on the fact that if the hydrogen atoms were not co-planar, then substitution derivatives (the substituting groups not containing asymmetric carbon atoms) should exist in enantiomorphic forms, differing in crystal form and in their action on polarized light; such optical antipodes have, however, not yet been separated.

The normal nitrate, Bi(N03)3.5H20, is obtained in large transparent asymmetric prisms by evaporating a solution of the metal in nitric acid.

It is seen that aldoses and ketoses which differ stereochemically in only the two final carbon atoms must yield the same osazone; and since d-mannose, d-glucose, and d-fructose do form the same osazone (d-glucosazone) differences either structural or stereochemical must be placed in the two final carbon atoms.3 It may here be noticed that in the sugars there are asymmetric carbon atoms, and consequently optical isomers are to be expected.

Of the tri-derivatives the symmetrical compounds boil at the lowest temperature, the asymmetric next, and the vicinal at the highest.