Sentence Examples with the word aluminium chloride

On reduction it yields butyro-lactone, and when CO condensed with benzene in the presence of aluminium chloride it yields chiefly -y-diphenylbutyro-lactone.

It may be synthetically prepared by the action of anhydrous aluminium chloride on a mixture of naphthalene and ethylene dibromide (R.

It may be obtained from storax by distillation with water, and synthetically by heating cinnamic acid with lime, by the action of aluminium chloride on a mixture of vinyl bromide and benzene, by removing the elements of hydrobromic acid from bromethylbenzene by means of alcoholic potash, or, best, by treating (-bromhydrocinnamic acid with soda, when it yields styrolene, carbon dioxide and hydrobromic acid.

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Acetyl acetone, CH 3 CO CH 2 CO CH 3, may be prepared by the action of aluminium chloride on acetyl chloride, or by condensing ethyl acetate with acetone in the presence of sodium (L.

It may be obtained synthetically by Fittig and Tollens's method (above); by Friedel and Craft's process, devised in 1877, of acting with aluminium chloride on a mixture of benzene and methyl chloride; this reaction leads to the production of higher homologues which may, however, break down under the continued action of the aluminium chloride; or by heating the toluene carboxylic acids obtained by oxidizing the higher homologues of benzene.

Sulphur chloride, S2C12, is obtained as a by-product in the manufacture of carbon tetrachloride from carbon bisulphide and chlorine, and may also be prepared on the small scale by distilling sulphur in a chlorine gas, or by the action of sulphur on sulphuryl chloride in the presence of aluminium chloride (0.

It can also be prepared by distilling meta-oxyuvitic acid with lime, or by the action of air on boiling toluene in the presence of aluminium chloride (C. Friedel and J.

Wurtz); by the action of nitrous acid on aniline; by passing oxygen into boiling benzene containing aluminium chloride (C. Friedel and J.