Sentence Examples with the word Syntheses

Marckwald (Ann., 93, 74, 331; 1894, 79, 14) has supported this formula from considerations based on the syntheses of the quinoline ring.

In the preceding instances the carboxyl group has been synthesized or introduced into a molecule; we have now to consider syntheses from substances already containing carboxyl groups.

This formula, notwithstanding many attempts at both disproving and modifying it, has well stood the test of time; the subject has been the basis of constant discussion, many variations have been proposed, but the original conception of Kekule remains quite as convenient as any of the newer forms, especially when considering the syntheses and decompositions of the benzene complex.

View more

Furthermore, it is in accordance with certain simple syntheses of benzene derivatives (e.g.

Of such syntheses we may notice: the condensation of sodium malonic ester to phloroglucin tricarboxylic ester, a substance which gives phloroglucin or trioxybenzene when fused with alkalis, and behaves both as a triketohexamethylene tricarboxylic ester and as a trioxybenzene tricarboxylic ester; the condensation of succinic ester, (CH2 C02C2H5)2, under the influence of sodium to succinosuccinic ester, a diketohexamethylene dicarboxylic ester, which readily yields dioxyterephthalic acid and hydroquinone (F.

Stas, in his syntheses of silver iodide, weighed the silver and the iodine separately, and after converting them into the compound he weighed this also.

Hitherto we have generally restricted ourselves to syntheses which result in the production of a true benzene ring; but there are many reactions by which reduced benzene rings are synthesized, and from the compounds so obtained true benzenoid compounds may be prepared.

One of the earliest red-hot tube syntheses of importance was the formation of naphthalene from a mixture of alcohol and ether vapours.

For other syntheses of hexamethylene derivatives, see Polymethylenes.

The constitution of the benzene ring, the isomerism of its derivatives, and their syntheses from aliphatic or openchain compounds, are treated in the article Chemistry.