Sentence Examples with the word Phthalic

There are three isomers: (1) ortho, or phthalic acid; (2) meta, or isophthalic acid; (3) para, or terephthalic acid.

KOnigs, and the observation that anthraquinone yielded oxyanthraquinones when treated in the cold with strong sulphuric acid, and the recent introduction of fuming sulphuric acid for the oxidation of naphthalene to phthalic acid, a process of great value in the manufacture of artificial indigo, may be noted.

This is obviously unsymmetrical, consisting of an aliphatic and an aromatic nucleus; Claus explained the formation of the same phthalic acid from the oxidation of either nucleus by supposing that if the aromatic group be oxidized, the aliphatic residue assumes the character of a benzene nucleus.

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An important oxidation synthesis of aromatic acids is from hydrocarbons with aliphatic side chains; thus toluene, or methylbenzene, yields benzoic acid, the xylenes, or dimethyl-benzene, yield methyl-benzoic acids and phthalic acids.

A notable example is provided by the phthaleins, which result by the condensation of phthalic anhydride with phenols.

Dorp (Ber.,1874,7,P.578) obtained orthobenzoyl benzoic acid by heating phthalic anhydride with benzene in the presence of aluminium chloride.

The A 4 acid exists in cis- and transforms. The trans-variety is produced by reducing phthalic acid, and the cis-acid by reducing 2.4 dihydrophthalic acid.

Von Baeyer's researches (commenced in 1886) on the reduced phthalic acids.

Unlike resorcin it does not give a fluorescein with phthalic anhydride.

He admitted the possibility of the formulae of Kekule, Claus, Dewar and Ladenburg, although as to the last di-trimethylene derivatives should be possible reduction products, being formed by severing two of the prism edges; and he attempted to solve the problem by a systematic investigation of the reduced phthalic acids.